महत्वपूर्ण शब्दावली परिभाषा (रसायन विज्ञान) - 2

हिन्दी	अंग्रेज़ी	परिभाषा

IAD	ion-assisted deposition; used to make optical coatings at low temperatures
आदर्श गैस	ideal gas	A gas in which the particles are infinitely small, have a kinetic energy directly proportional to the temperature, travel in random straight lines, and don't attract or repel each other. Needless to say, there's no such thing as an ideal gas in the real world. However, we use ideal gases anyway because they make the math work out well for equations that describe how gases behave.
आदर्श गैस नियम	ideal gas law	PV=nRT
आदर्श विलयन	ideal solution	A solution in which the vapor pressure is directly proportional to the mole fraction of solvent present
	IET	intramolecular electron transfer
	immersion lens	a hemispherical lens which is used to decrease the detector size. Essentially, the image is reduced without loss of resolution.
	immiscible	When two substances don't dissolve in each other. Think of oil and water. They're immiscible. Organic compounds and water are frequently immiscible.
	incandescence	when materials are self-luminous solely owing to their high temperatures
	inclusion	when something is incorporated in a crystal, either in a lattice site or interstitial site.
	indicator	A compound that turns different colors at different pH values. We generally like to have the color change at a pH of around seven because that's where the equivalence point of a titration is.
	inertia	the tendency of a body to maintain its state of rest or uniform motion
	infrasonic	sound waves with smaller frequency than we can hear (20 Hz)
	inhibitor	A substance that slows down a chemical reaction.
अकार्बनिक यौगिक	inorganic compound	Any compound that doesn't contain carbon (except for carbon dioxide, carbon monoxide, and carbonates).
अविलेय	insoluble	When something doesn't dissolve.
	intercalation	incorporation of a foreign atom into some crystal lattice (usually in the interstitial spaces)
	intermediate	A molecule which exists for a short time in a chemical reaction before turning into the product.
अन्तर-आणविक बल	intermolecular force	A force that exists between two different molecules. Examples are hydrogen bonding (which is strong), dipole-dipole forces (which are kind of weak), and London dispersion forces (a.k.a. Van der Waal forces), which are very weak.
	intrinsic semiconductor	a material in which the band gap is small enough to make the material a semiconductor
	Iodate ion	IO3(-)
आयनिक बन्ध	ionic bond	A bond formed when charge particles stick together.
	ionic migration	A way of conducting electricity where you have charged particles moving through a matrix of some sort.
आयनन की उर्जा	ionization energy	The amount of energy required to pull an electron off of a gaseous atom.
	iris diaphragm	used in fluorimeters to control the amount of radiation from the source; consists of a series of overlapping plates arranged to move so that a roughly circular opening of variable size is produced. This is achieved by maintaining a nearly constant angle between the edges of adjacent plates.
अनुत्क्रमणीय अभिक्रिया	irreversible reaction	A chemical reaction in which the reagents make products but the products can't reform reagents. Most chemical reactions in basic chemistry classes are thought of as being irreversible.
	Irtran 1	Magnesium fluoride
	Irtran 2	zinc sulfide
	isenthalpic	a change that occurs without a change in enthalpy
	isotherm	a curve on a vol. vs. temp. vs. pressure diagram that corresponds to a single temperature
	isotonic solutions	Solutions containing the same osmotic pressure.
समस्थानिक	isotope	When an element has more than one possibility for the number of neutrons, these are called isotopes. All known elements posess isotopes. For the record, the word "isotope" doesn't imply that something is radioactive. TV told you that, and TV is stupid.
	isotopomer	having the same topography
	isotropic medium	a medium in which the waves travel at equal speed independantly of which direction they travel.
	Jones reductor	a metal reductor column filled with zinc
	joule	1 kg sq.meter/sq. second
केल्विन	Kelvin	A unit used to measure temperature. One Kelvin is equal in size to one degree Celsius. To convert between degrees Celsius and Kelvins, simply add 273.15 to the temperature in degrees Celsius to get Kelvins.
	Kepler’s laws of planetary motion	1) The path of each planet about the sun is an ellipse with the sun at one focus. 2) Each planet moves so that an imaginary line drawn from the sun to the planet sweeps out equal areas in equal periods of time. 3) The ratio of the squares of the periods of any two planets revolving about the sun is equal to the ratio of the cubes of their mean distances to the sun.
	ketone	A molecule containing a R-CO-R' functional group. Acetone (dimethyl ketone) is a common one.
गतिज उर्जा	kinetic energy	The energy due to the movement of an object. The more something moves, the more kinetic energy it has.
	Kirchoff’s rules	1) At any junction point, the sum of the currents entering the junction must equal the sum of the currents leaving the junction. 2) The sum of the changes in potential around any closed path of a circuit must be zero.
	Kjeldahl method	oxidize a sample to turn nitrogen gas to ammonium ions; used to determine the amount of nitrogen in a sample.
	klystron	microwave generator
	Knoop hardness	a static measure of material hardness based on the size of impression made in the material with a pyramidal diamond indenter under specific conditions.
	Kronecker delta	when you take the integral over all space of a wavefunction and its complex conjugate, you get this. If it is equal to one, the wavefunctions are the same.
	KRS-5	thallium bromoiodide
	Lamb formula	used to find the shielding constants for nuclei.
	Lambertian radiator	when a light emitted from a source or scattered from a surface has a radiance that is independant of viewing angle
	laminar flow	when the neighboring layers of a moving liquid slide by each other smoothly
	Langmuir-Blodgett film	lipid bilayer sorts of films. They can be made of any size and almost any thickness. They are plated on solid surfaces by taking these surfaces and dipping them into a container which has a liquid with the film floating on top.
	Lanthanide contraction	The tendency of the lanthanides to get small when you go from left to right in the periodic table.
	Larmour frequency	precessional angular velocity of an atom. Equal to the product of the magnetogyric ratio and strength of the applied magnetic field.
	laser desorption mass spectrometry (LDMS)	when you take a sample and hit it with a laser, you send the particles that come flying off and send them into a mass-spec.
	laser threshold damage level (LDT level)	the intensity at which a laser will damage a surface; coated surfaces have a lower LDT level than uncoated surfaces. My dad did a lot of research on stuff like this.
	latent heats	the heats of fusion and evaporation
	lateral magnification	the height of an image divided by the height of the object
	lattice	The three-dimensional arrangement of atoms or ions in a crystal.
	lattice energy	The energy released when one mole of a crystal is formed from gaseous ions.
	lattice energy	the energy required to separate completely the ions in an ionic solid.
उर्जा संरक्षण का नियम	law of conservation of energy	The amount of energy in the universe never changes, ever. It just changes form.
द्रब्यमान संरक्षण का नियम	law of conservation of mass	The amount of stuff after a chemical reaction takes place is the same as the amount of stuff you started with.
	law of universal gravitation	every particle attracts every other particle with a force that is proportional to the product of the masses and inversely proportional to the square of the distance between them.
	LDOS	local density of states
ला शैतालिए का सिद्धान्त	Le Chatlier's Principle	When you disturb an equilibrium (by adding more chemical, by heating it up, etc.), it will eventually go back into equilibrium under a different set of conditions.
	leakage current	a current that travels along an unintended path
	LEED	low-energy electron diffraction; can be used to investigate surface structures
	length contraction	the idea that the length of an object is measured to be shorter when it is moving than when it is at rest. A consequence of relativity.
	Lenz’s law	an induced emf always gives rise to a current whose magnetic field opposes the original change in magnetic flux.
	Lewis acid	An electron-pair acceptor (carbonyl groups are really good ones)
	Lewis base	An electron-pair donor. Things with lone pairs like water and ammonia are really good ones.
	Lewis structure	A structural formula that shows all of the atoms and valence electrons in a molecule.
	ligand	A molecule or ion that sticks to the central atom in a complex. Common examples are ammonia, carbon monoxide, or water.
	light pipe	a hollow cone with highly reflecting walls which collects light at one end and channels it through successive reflections to the other end. When the walls are changed to a highly absorptive material, it can be used as a light collector.
	limiting reagent	If you do a chemical reaction and one of the chemicals gets used up before the other one, the one that got used up is called the "limiting reagent" because it limited the amount of product that could be formed. The other one is called the excess reagent.
	line spectrum	A spectrum showing only certain wavelengths.
	linear polarizer	changes unpolarized light to polarized light.
	linkage isomer	isomers where a ligand differs in which atom is bonded to the metal atom.
	liquid crystal	a substance that has liquid-like long range disorder but some crystal-like aspects of short range order.
	Littrow prism	used in laser cavities to select oscillation at a particular frequency. For a particular wavelength the refracted ray on entering the prism travels normally to the exit face. The exit face is reflectively coated so that this beam travels back along the original path.
	London dispersion force	The forces between nonpolar atoms or molecules which is caused by momentary induced dipoles. It's real weak.
	lone pair	two electrons that aren't involved in chemical bonding. Also frequently referred to as an "unshared pair".
	longitudinal relaxation time (T1)	the time it takes after a pulse in NMR for the nuclei to get the same spin up/spin down ratio they had before the pulse. Also called spin-lattice relaxation.
	longitudinal wave	when the vibration of the particles in the medium move in the same direction as the motion of the wave, for example, a sound wave in air.
	long-range coupling	an NMR term, this describes the fact that sometimes you get spin-spin coupling between protons over distances longer than three bond lengths. This usually happens in highly conjugated systems, and the coupling constants are generally less than 3 Hz.
	lyophilic	solvent-attracting
	lyophobic	solvent-repelling
	magnesia	magnesium oxide
	magnetic equivalence	when a group of nuclei are chemically equivalent and have identical spin-spin interactions.
	magnetogyric ratio	this is an empirical factor with which you can find the magnetic moment of a nucleus with a non-zero magnetic moment. It cannot be calculated because there is not enough knowledge about how the nucleus works.
	main-block elements	Groups 1,2, and 13-18 in the periodic table. They're called main block elements because the outermost electron is in the s- or p- orbitals. What that has to do with the term "main block" is unclear to me, but hey, that's life.
	masking agent	a chemical added to a mixture which will block any impurity from affecting the chemical analysis; this is very handy if you have a transition metal ion which may interfere with the analysis of another transition metal ion.
द्रब्यमान	mass	The amount of matter in an object. The more mass, the more stuff is present.
	mass defect	The difference between the mass of an atom and the sum of the masses of its individual components. Atoms usually weigh a little less than if you added up the weights of all the particles. This is because that extra mass was converted into the energy which holds the atom together (see "binding energy")
	Maxsorb	A form of high surface area activated carbon manufactured by Kansai Coke and Chemicals, Japan.
	MCT	mercury-cadmium-telluride detector. Used in doing IR spectroscopy.
	mean free path	the average distance traveled by a gas molecule between collisions.
	mechanical waves	waves that travel in a material medium, such as water waves.
	mechanism	A step-by-step sequence that shows how the products of a reaction are made from the reagents. Mechanisms are very frequently shown during organic chemistry.
	mercury arc	an IR source that operates from 1-100 atmospheres. Good for producing IR radiation from 50-1400 microns.
	mercury diffusion pump	in this sort of device, mercury is boiled to produce a very high vacuum. The principle working here is that the heated mercury vapor is dragging the molecules of gas in the system, and getting them out of the place you are trying to maintain a high-vacuum.
	mesophase	a phase intermediate between liquid and solid. May also be a smectic phase.
	metal reductor column	a metal-filled column which is used to reduce metals in solution that are passed through it.
	metallofullerenes	fullerenes which contain metal atoms or ions in them. Commonly, many fullerenes are produced with metal impurities because the metal acts as a catalyst for their formation; this is especially true for nanotubes.
	mica	potassium aluminosilicate
	microgravimetry	When you go about trying to figure out the mass of something that doesn’t change much in weight. Usually you need very sensitive equipment that costs a lot.
	microporous carbon	A form of carbon in which you see many small pores in the surface. Generally, the micropore walls consist of graphitic crystallites, causing them to have a hydrophobic nature.
	mie scattering	similar to Rayleigh scattering, except that it is dependant on the shape of the particles.
	Millipore filter	a water purification filter which has changeable filter cartridges. Depending on how pure the water needs to be, the filter sensitivity can be changed.
	mixed conductor	A conductor in which both ionic migration and electrons or positive holes in the materials is responsible for current flow.
	MLAR	multi-layer antireflection coating
	moderator	a material used in a nuclear reactor to slow the neutrons; heavy water and graphite rods are two common materials.
	modulus	a constant which expresses a force
	Mohr titration	use of a chromate ion in a precipitation titration; endpoint is reached when the precipitate starts to form.
मोललता	molality	The number of moles of solute per kilogram of solvent in a solution. This is a unit of concentration that's not anywhere near as handy or common as molarity.
	molar absorptivity	represents the absorbance of a 1M solution of analyte in a 1 cm. cell; used as a constant in Beer’s Law.
मोलर द्रब्यमान	molar mass	The mass of one mole of particles.
मोलर आयतन	molar volume	The volume of one mole of a substance at STP. If you believe that everything is an ideal gas, this is always 22.4 liters. Unfortunately, there's no such thing as an ideal gas.
मोलरता	molarity	A unit of concentration equal to moles of solute divided by liters of solution.
मोल	mole	6.02 x 1023 things.
	mole fraction	The number of moles of stuff in a mixture that are due to one of the compouds.
	mole ratio	The ratio of moles of what you've been given in a reaction to what you want to find. Handy in stoichiometry.
	molecular beams	a narrow stream of molecules which is directed toward other molecules
आणविक यौगिक	molecular compound	A compound held together by covalent bonds.
	molecular dynamics (MD)	A way of figuring out how molecules will behave through the use of quantum mechanical methods. Different in form and method from semi-empirical methods such as the Monte Carlo method.
आणविक सूत्र	molecular formula	A formula that shows the correct quantity of all of the atoms in a molecule.
	monatomic ion	An ion that has only one atom, like the chloride ion.
	monochromator	light goes in, hits a dispersing element (such as a diffraction grating or prism) and some portion of light is allowed out the other side.
	monodisperse	when a polymer has only one molecular mass. They are typically generated by natural processes.
	Monte Carlo method	a semi-empirical method for determining molecular dynamics of a system. What you do is to move the particles via a random method. Whether or not this new configuration is accepted depends on 1) If the PE is not greater than before the change, it is accepted. 2) If it is accepted, it is accepted in proportion to how much the potential change is for all the particles in the system.
	MOST	Korean Ministry of Science and Technology
	mull	a finely ground powder dispersed in an oil for IR spectroscopy.
	multimeter	a device that can measure voltage, current and resistance; may also be called a volt-ohm-meter (VOM)
	multiplicity	Equal to 2S+1
	nanotube	A long cylindrical structure related to the fullerenes. The structure of these rods appears to be a stacked graphite ring structure on the outside, and a randomized graphitic crystal structure on the inside. Generally, these tubes form best at temperatures above 1200C, and not at all under 200C.
	nascent	beginning to develop, immature.
	Nd	AG laser: A laser with a Nd/Yttrium aluminum garnet rod.
	nebulizer	a way of producing an aerosol for AAS.
	Neel temperature	where anti-ferromagnetic transitions occur
	Nernst glower	produces IR light to 15 microns. A hollow rod about three centimeters long and one millimeter diameter made from ZrO2 and Y2O3 mixed with CeO2 or ThO2. Operated at temperatures from 1500-2000K.
	Nernst heat theorem	entropy change of a transformation approaches zero as the temperature approaches zero
	neutralization reaction	The reaction of an acid with a base to form water and a salt.
	neutrino	a particle with no charge or mass that is given off during beta decay
	newton	kg m/second squared; unit of force
	Newton’s rings	when a curved glass surface is placed in contact with a flat glass surface, a series of concentric rings is observed when illuminated from above with monochromatic light. This is caused by the reflection of light from the surfaces, giving constructive and destructive interference. This phenomena can be used to test whether or not a lens is properly ground.
	NIST	National Institute of Standards and Technology
	node	A location in an orbital where there's no probability of finding an electron.
	nodes	points of destructive interference between two waves.
	nonconservative field	describes the electric field produced by a changing magnetic field.
	nonpolar covalent bond	A covalent bond where the electrons are shared equally between the two atoms.
	normal boiling point	The boiling point of a substance at 1.00 atm.
	normal melting point	The melting point of a substance at 1.00 atm.
नार्मलता	normality	The number of equivalents of a substance dissolved in a liter of solution.
	n-type semiconductor	donor band that is full donates to another empty band, giving rise to conductivity
नाभिकीय संलयन	nuclar fusion	When many small atoms combine to form a large one. This occurs during a thermonuclear reaction.
	nuclear fission	This is when the nucleus of an atom breaks into many parts.
	nuclear quadrupole coupling constant	a molecular parameter which provides a sensitive probe of electronic and surrounding molecular structure near some quadrupolar nucleus of interest.
नाभिकीय अभिक्रिया	nuclear reaction	Any reaction that involves a change in the nucleus of an atom. Nuclear reactions take loads of energy, which is why you don't see them much around the lab.
	nucleation	when a small particle or molecule spurs the condensation of a vapor or solid. Can occur with solid or liquid particles, or even ions.
	nucleon	A particle (such as proton or neutron) that's in the nucleus of an atom.
	nujol	a high-boiling petroleum oil often used as a solvent for IR spectroscopy because it is relatively free of IR absorption bands.
	observable	a physically-measurable property of a system
	occlusion	when a impurity is “surrounded” by the material of interest, but not actually incorporated into the crystal lattice.
अष्टक नियम	octet rule	All atoms want to be like the nearest noble gas. (Well, they all want to have the same number of valence electrons, anyway). To do this, they either gain or lose electrons (to form ionic compounds) or share electrons (to form covalent compounds).
	odd b	if g(-x)=-g(x), then g is an odd function.
	off-axis chromatic aberration	when chromatic aberration results in a difference in image size.
	Ohm’s law	V=I/R (voltage equals current/resistance)
	operator	a rule that transforms a given function into another function
	Opperman source	an IR source that consists of a ceramic tube with an internal noble metal heater. It requires no preheating.
	optic axis	the direction in a birefringent crystal along which no splitting of the beam occurs
प्रकाशीय समावयवता	optical isomerism	Isomerism in which the isomers cause plane polarized light to rotate in different directions.
	orbital	This is where the electrons in an atom live.
	ordinary ray	the beam that does not deviate upon being split by a birefringent crystal
कार्बनिक यौगिक	organic compound	A compound that contains carbon (except carbon dioxide, carbon monoxide, and carbonates)
परासरण	osmosis	The flow of a pure liquid into an area of high concentration through a semi-permeable membrane.
	Ostwald process	a catalytic process which is used to make nitric acid from ammonia.
	Ostwald ripening	coarsening in crystal structures; it is an inherent property of crystals at a solid-liquid interface. The coarsening and enarging of crystals at surfaces is driven by a thermodynamic driving force to reduce the surface to volume ratio; this in turn lowers the interfacial or line energy.
आक्सीकरण	oxidation	When a substance loses electrons.
आक्सीकरण संख्या	oxidation number	The apparent charge on an atom.
	oxygen-free high-conductivity copper (OFHC)	a form of copper used frequently for instrument applications because of high purity, good conductivity and resistance to hydrogen embrittlement.
	PAH	polyaromatic hydrocarbon
	paramagnetic	a paramagnetic material has unpaired electrons; when such a material which has molecules with permanent dipole moments is placed in an external field, they orient themselves. When there is no field, the molecules are randomly oriented.
	parity operator	replaces each cartesian coordinate with its negative
	parrafins	normal alkanes with no functionality and no branching.
आंशिक दाब	partial pressure	The pressure of one gas in a mixture. For example, if you had a 50:50 mix of helium and hydrogen gases and the total pressure was 2 atm, the partial pressure of hydrogen would be 1 atm.
	pascal	newton/sq. meter
	Pascal’s triangle	the diagram that gives the peak intensity ratios for NMR and ESR. It does have the appearance of a triangle, and each row has numbers which correspond to the sum of the numbers on top of it.
	passband	the primary wavelength interval of transmission of a gas filter.
पाली का अपवर्जन का सिद्धान्त	Pauli exclusion principle	No two electrons in an atom can have the same quantum numbers.
	pellicles	beam-splitting mirrors made of high-tensile-strength polymer stretched over a flat metal surface
	pencil angle	a half angle which describes the rays emanating from a point at the edge of an object
	Penta prisms	deviate a ray of light by 90 degrees without inversion or reversion. Called penta prisms because they are pentagonal solids.
	percent yield	The actual yield divided by the theoretical yield, times 100.
आवर्त काल	period	A row (left to right) in the periodic table.
आवर्तता का नियम	periodic law	The properties of elements change with increasing atomic number in a periodic way. That's why you can stick the elements into a big chart and have the elements line up in nice families.
	PES	potential energy surface
पीएच	pH	-log[H+]
फेज	phase	The state of a compound (solid, liquid, or gas)
फेज आरेख	phase diagram	A chart which shows how the phase depends on various conditions of temperature and pressure.
	phase velocity	the velocity at which the crests of a wave move.
	phonon	a lattice vibration
	phosphorescence	spontaneous emission persists for a long time after the exciting radiation ceases. This long-lived relaxation arises from the fact that the transition being made here is a forbidden inter-system crossing.
	photoconductive detector	a change in number of incident photons causes a fluctuation in the number of free charge carriers in a semiconductor. Electrical conductivity is inversely proportional to the number of incident photons.
	photoelastic effect	sensitivity of the optical dielectric response to changes in density.
	photoelectric effect	ejection of electrons from metals when exposed to UV radiation.
	photoelectron spectroscopy (PES)	measures the ionization energies of molecules when electrons are ejected from different orbitals; it uses these to infer the orbital energies. UV photoelectron spectroscopy is for hitting more energetic molecules, and X-Ray photoelectron spectroscopy is handy for pulling off the core electrons.
	photomultiplier tube (PMT)	when light comes in, it hits an anode surface that releases many electrons. When nine of these are placed in series, there is a huge increase in the original signal. The anode surfaces are called dynodes.
	photosensitized reaction	when the reagent is not actually what absorbs light; instead, a photosensitizer picks up light and transfers the energy to the reagents.
	photovoltaic detector	a change in the number of photons incident of a p-n junction causes fluctuations in the voltage generated by the junction.
भौतिक गुण	physical property	A property which can be determined without changing something chemically. If that doesn't make sense, see the definition of "chemical change".
	physical vapor deposition (PVD)	get a source material into the vapor phase and then allow the molecules to condense on the surface of a thin film
पाई बन्ध	pi-bond	A double bond.
	piezoelectric effect	the phenomenon in which a crystal under the action of a mechanical stress becomes electrically charged, with opposite charges at the two ends of the crystal. Does not occur in centrosymmetric crystals, except for those in the cubic 432 group.
	plastic deformation	the strain at which a solid can no longer regain its original shape.
	Pockel’s cell	an optical phase modulator
	Poise	the cgs unit of viscosity; equal to dyne*sec/centimeters squared
	polar covalent bond	A covalent bond where one atom tries to grab the electrons from the other one. This occurs because the electronegativities of the two atoms aren't the same.
	polyampholyte	when a macromolecule has mixed anion and cation character.
बहुपरमाणवीय	polyatomic	contains more than one atom.
	polydisperse	When a polymer exists over a wide range of molecular masses; characteristic of man-made polymeric materials.
	polymer	A molecule containing many repeating units. Plastics are polymers and are formed by free radical chain reactions.
	polymorph	the varying structures of solid materials when the temperature is changed
	polyprotic acid	An acid that can give up more than one hydronium ion. Examples are sulfuric acid and phosphoric acid.
स्थितिज उर्जा	potential energy	The energy something has because of where it is. Things that are way up high have more potential energy than things that are way down low because they have farther to fall.
	Poynting vector	the energy an EM wave transports per unit time per unit area. Denoted as the vector S.
	precision	A measurement of how repeatable a measurement is. The more significant figures, the more precise the measurement.
दाब	pressure	Force/area
	pressure amplitude	represents the maximum and minimum amounts by which the pressure varies from normal ambient pressure. Usually used in describing shock waves or sound waves.
	primary creep	when you put strain on a substance, this is the movement that is still recoverable.
उत्पाद	product	The thing you make in a chemical reaction.
	proton decoupling	when you are doing C-NMR, you have the possibility that the spins of the carbon and that of the protons will couple, and the spectrum would then be very hard to understand. In this method, you get rid of any coupling by following the initial pulse with a pulse that randomizes the spins of the protons; in this way, the signal averaging gets rid of any spin coupling between them. It does make it easier to see how many carbons there are, although it makes it impossible to integrate peak heights to figure out the abundances of each equivalent carbon.
	p-type semiconductor	low-lying acceptor band gives rise to conductivity
	pulsed gradient spin echo (PSGE)	An NMR technique which is used to study the speed of liquid motion.
	pyranose	a six-membered ring sugar molecule.
	pyrolytic	breaking apart through heat
	pyromagnetic	when you can change magnetic properties of a compound through heating
	quadrupole	a “double dipole”; a molecule with a quadrupole will have no dipole moment because the two dipoles present in the molecule cancel each other out. A good example is carbon dioxide.
	quadrupole mass filter	used in mass spec, this tool has four voltage-carrying rods which serve to give ions which travel between them oscillations. Only ions with the right mass/charge ratio (m/z) can undergo these oscillations without hitting one of these rods.
	quantum number	1) n is the principal quantum number. n has possible values of 1,2,3... 2) l is the orbital quantum number, having values of 0....n-1 3) ml is the magnetic quantum number, having values of -l, -l+1....l 4) ms is the spin quantum number, having a value of either 1/2 or -1/2.
क्वान्टम सिद्धान्त	quantum theory	The branch of physical chemistry that describes how energy can only exist at certain levels and makes generalizations about how atoms behave from this assumption.
	quarter wave plate	used to change linearly polarized light to circularly polarized light
	Q-value	the total energy released by the radioactive disintegration of a nucleus
	QWOT	quarter-wave optical thickness
	radiant power	total amount of energy emitted by a light source per second
रेडियो सक्रिय	radioactive	When a substance has an unstable nucleus that can fall apart, it's referred to as radioactive.
राउल्ट का नियम	Raoult's Law	The vapor pressure of a solution is directly proportional to the mole fraction of the solvent.
	rate determining step	The slowest step in a chemical reaction.
	rate law	A mathematical expression for the speed of a reaction as a function of concentration. A hint: It's usually true that things go faster if you have more stuff in the first place.
	Rayleigh scattering	when light is scattered by particles much smaller than the wavelength. The shorter the wavelength, the more intense the scattering.
	RC circuit	a circuit that uses both resistors and capacitors
	reactive plasma deposition (RPD)	similar to CVD, except that an rf plasma helps the decomposition/recombination process of the reactants.
	rectifier	a device that turns ac power into dc power
	redox reaction	A reaction that has both an oxidation and reduction.
	reduced mass	=m1m2(m1+m2)
	refractory metals	include tungsten, tantalum and molybdenum; used for electrode materials because they have a low, uniform surface potential, do not oxidize, and are bakeable
	relativity principle	the basic laws of physics are the same in all inertial reference frames
	relaxation times	consist of T1 (longitudinal relaxation time) and T2 (transverse relaxation time). Basically, the relaxation times correspond to the time it takes after the pulse in NMR or other spectroscopic tecniques for the molecules to go back to their Boltzmann distribution of states.
	REMPI	resonance enhanced multi-photon ionization
	resistance thermometer	uses the dependance of electrical resistance on temperature to measure the temperature.
	resolution (of a lens)	the ability of a lens to produce distinct images of two point objects very close together
	resonance	what happens when you have two or more oscillators connected in some way; these oscillators tend to get the same frequency because this gives more efficient energy transfer between them. This coupling of frequencies is resonance.
	resonance structure	When more than one valid Lewis structure can be drawn for a molecule, these structures are said to be resonance structures. Resonance structures arise from the fact that the electrons are delocalized.
	resonant two-photon ionization (R2PI)	A process in which two photons strike a sample and ionize the molecules. One good thing about this process is that the product ions generally have known structure.
	rest mass	the mass of an object as measured in a reference frame where it is at rest.
	Reststrahlen filter	utilizes the phenomena that reflections of white light from crystal surfaces will contain only one region of the spectrum
	resultant	the sum of two or more vectors.
	retroreflector	see corner-cube prism
उत्क्रमणीय अभिक्रिया	reversible reaction	A reaction in which the products can make reagents, as well as the reagents making products.
	reversion	right-to-left reversion of an image
	Reynold’s number	characterizes the onset of turbulence in a tube. Re = 2vr(rho)/n, where n=viscosity, r=radius of tube, rho=density of the fluid, v=velocity of the fluid; If Re<2000, there is laminar flow; if Re>2000, there is turbulent flow.
	RHME	rotating hanging meniscus electrode
	rhomboid prism	used for lateral deviation of a light ray
	rolling friction	the friction from when one body rolls across a surface; generally much smaller than the sliding friction.
वर्ग मूल माध्य वेग	root mean square velocity (RMS velocity)	The square root of the average of the squares of the individual velocities of the gas particles in a mixture. To put it in a way that a normal human can understand, it's the average of how fast the particles in a gas are going (assuming you ignore the direction they're traveling in).
	root-mean-square speed (rms)	the square root of the average of the squared speeds of gas molecules in a sample.
	Roots blower	a type of vacuum pump capable of pressures down to .01 torr.
	rotating disk electrode (RDE)	method to determine kinetics of electrodes. If you have the electrode be a rotating disk, the current of the sample can be related to the speed of rotation.
	Rowland ghosts	spurious intensity maximum spurred from periodic errors in the spacing of the ruled grooves in a diffraction grating.
	RPM	radical pair mechanism
	ruby	aluminum oxide, Al2O3
लवण	salt	An ionic compound.
	SAM	self-assembled monolayer
	sapphire	Al2O3, aluminum oxide
	SATP	standard ambient temperature and pressure; corresponds to 25 C, 1 bar
संतृप्त	saturated	When the maximum amount of solute is dissolved in a liquid
	scalar	a quantity that is specified completely by giving a number
	SCE	standard calomel electrode
	Schott IRG 11	calcium aluminate; transmits light between .3-5.5 microns
	Schott IRG 2	germanate; transmits light between .3-4.6 microns
	Schott IRG N6	calcium aluminosilicate; transmits light between .3-4.75 microns
	SCRF	self-consistent reaction field method. A method for calculating the energies of molecules in a reaction
उष्मागतिकी का द्वितीय नियम	Second law of thermodynamics	Whenever you do something, the universe gets more random.
	second law of thermodynamics	the entropy of an isolated system increases in the course of a spontaneous change
	Seeback effect	when a metal has a temperature gradient, it has a voltage. The difference in thermally induced voltages of two metals will cause a net voltage in a junction.
अर्धचालक	semiconductor	A substance that conducts electricity poorly at room temperature, but has increasing conductivity at higher temperatures. Metalloids are usually good semiconductors.
	SERR spectroscopy	surface-enhanced resonance Raman spectroscopy; a Raman method used because it has excellent selectivity to the microscopic environment and orientation of things adsorbed on surfaces.
	SERS	surface-enhanced Raman scattering
	SHE	standard hydrogen electrode; defined as having 0V.
	shear modulus	the modulus of rigidity; concerned with the elastic deformation of a body in which an applied force results in the shape of a body.
	SHG	second harmonic generation
	shielded	when the sigma value in NMR is greater than zero. Deshielding is when the value is less than zero.
	shielding effect	The outer electrons aren't pulled very tightly by the nucleus because the inner electrons repel them. This repulsion is called the shielding effect, and can be used to explain lots of neat-o stuff.
सिग्मा बन्ध	sigma bond	A real fancy way of saying "single bond"
	significant figure	The number of digits in a number that tell you useful information. For example, when you weigh yourself on a bathroom scale, it says something like 150 pounds rather than 150.32843737 pounds. Why? Because the thing can only weigh accurately to the nearest pound. Any other digits that are on this number don't mean anything, because they're probably wrong anyway.
	silicon controlled rectifier	a switching device; in the on state it has low resistance and in the off state it has very high resistance.
	single-displacement reaction (a.k.a. single replacement reaction)	When one unbonded element replaces an element in a chemical compound. These are frequently redox reactions.
	size exclusion chromatography (SEC)	where you separate mixtures based on the sizes of the molecules.
	SLAR	single layer antireflection coating
	smectic	a smectic phase is when the molecules align themselves into a pseudo-crystalline lattice. Liquid crystals are one example.
	Snell’s law	n1sin(theta1)=n2sin(theta2); describes refraction.
	softening point	the point at which a glass can be molded or worked
	sol	a stable dispersion of either solids in liquids or solids in solids.
	solenoid	a long coil of wire consisting of may loops; when current flows through it, the magnetic field resembles that of a bar magnet.
बिलेयता	solubility	A measurement of how much of a solute can dissolve in a liquid.
बिलेयता गुणनफल स्थिरांक	solubility product constant	Abbreviated Ksp, this value indicates the degree to which a compound dissociates in water. The higher the solubility product constant, the more soluble the compound.
विलेय	solute	The solid that gets dissolved in a solution.
विलायक	solvent	The liquid that dissolves the solid in a solution.
	space-charge effect	used to describe particle beam aberrations, it arises from the natural repulsion of particles of like charge; a focused beam will disperse, giving a diffuse image.
	spatial coherence	how much the waves are in step as they leave a laser cavity.
	special theory of relativity	1) The basic laws of physics are the same in all inertial reference frames. 2) Light propagates through empty space with a definite speed c independant of the speed of the source or observer.
	specific gravity	the ratio of the density of a substance at 4 C to that of water at 4 C.
विशिष्ट उष्मा धारिता	specific heat capacity	The amount of heat required to increase the temperature of one gram of a substance by one degree.
	spectator ions	The ions in a reaction that don't react.
	speed of sound	equal to the square root of the bulk modulus/density of the medium. As temperature rises, so does the speed of sound.
	sphere	radius=4pi(r squared), volume=4/3pi(r cubed)
	spherical aberration	the variation of focus with aperture in which a ray through the edge of the lens intersects the axis at a point other than the paraxial focus.
	spinel	magnesium aluminate, MgAl2O4.
	spin-spin coupling constant (J)	defines how much of an interaction you have between nuclei in a molecule. Gives rise to the fine structure in NMR.
	spontaneous change	A change that occurs by itself. All exothermic reactions are spontaneous. However, this doesn't mean that all exothermic reactions are fast. The combustion of gasoline is spontaneous, but not very fast unless you add a little energy.
	SPT	sputtering; allow a material into the vapor phase to condense into a thin film
	sputtering	see SPT
	standard state	the pure form of a substance at 1 bar pressure for any given temperature.
मानक ताप व दाब	standard temperature and pressure	One atmosphere and 273 K.
	steric hindrance	This is the idea that the functional groups on big molecules get in the way of a chemical reaction, making it go slower. Imagine a fat guy trying to get into a Honda Prelude - that's steric hindrance.
	stoichiometry	The art of figuring how much stuff you'll make in a chemical reaction from the amount of each reagent you start with.
	stopband	the primary region of reflection or absorption of a rejection filter.
	STP	See standard temperature and pressure.
	STP	standard temperature and pressure; corresponds to 0C, 1 atm.
	streamline	the path taken by any particle in a steady, laminar flow.
	strong acid	An acid that fully dissociates in water
	strong nuclear force	The force that holds the nucleus together. As the name suggests, this force is strong.
	structural formula	See Lewis structure.
उर्ध्वपातन	sublimation	When a solid can change directly into a gas. Dry ice does this.
	superconductor	A material which has no resistance to electricity. When passing current through a superconductor, there is no loss of electrical power due to these materials.
अतिशीतलन	supercooling	When you cool something below its normal freezing point
	supercritical liquid	a liquid which exists at temperatures above the normal boiling point; this is brought about through high pressure. Reactivity of solutes in these liquids can be changed drastically with minor changes in temperature and pressure.
	superfluid	a fluid that flows without viscosity (ex: He-II)
	superhigh surface area carbon	any carbon which has a specific surface area greater than 2630 square meters per gram
	superionic materials	Materials which exist largely in the ion phase. These are extremely useful in making conductors which work via ionic migration.
अतिसंतृप्त	supersaturated	When more solute is dissolved in a liquid than is theoretically possible. This doesn't happen much, as you might imagine.
	supersaturated vapor	A vapor which will spontaneously begin to condense in the presence of nucleation centers.
पृष्ट तनाव	surface tension	A measurement of how much the molecules on a liquid tend to like to stick to each other. If something has a high surface tension, it likes to bead up.
	surface tension	(gamma); the force F per unit length L that acts across any line in a surface, tending to pull the surface closed.
	surfactant	a species that is active between two phases. It accumulates at the interface and changes the surface tension.
	suspension	A mixture that looks homogeneous when you stir it, but where the solids settle out when you stop. Mud is a very short-lived suspension, while peanut butter is a very long-lived suspension.
	syngas	a mixture of gases (largely carbon monoxide and hydrogen) that results from heating coal in the presence of steam. Can be used as a fuel.
	synthesis	When you make a big molecule from two or more smaller ones.
	system	Everything you're talking about at the moment.
	TDFS	time-dependent fluorescence shifts
	TEM	transmission electron microscopy. What you do is take the sample, grind it up, then place an aqueous suspension of it on a grid where the electron microscope can get at it.
ताप	temperature	A measurement of the average kinetic energy of the particles in a system.
	temporal coherence	how much waves stay in step along a beam path
	theoretical plates	represents how many times you do a separation in purification; can be used to describe column chromatography, GC, or HPLC.
	theoretical yield	The amount of product which should be made in a chemical reaction if everything goes perfectly.
	thermal motion	chaotic, random motion of molecules due to the temperature
	thermal neutrons	neutrons that have not been slowed down and have reached equilibrium with matter at room temperature
	thermionic emission	you can get a current to flow from a heated filament to a positive electrode in a vacuum; this emission is simply electrons flowing from the filament to the positive electrode.
	thermistor	a substance which changes its resistance with temperature. Those developed as infrared detectors are known as bolometers.
	thermocouple	two metals are put together side by side when heated, one metal expands more than another due to differences in the coefficients of thermal exansion, and the strip bends. This can be used as a switch, as in a thermostat.
उष्मागतिकी	thermodynamics	The study of energy
	thermogravimetric analysis (TGA)	when you heat a sample to observe weight changes; used when studying the loss of waters of hydration or CO2.
	thermoplastics	plastics that can be softened by heating and return to their original state on cooling.
	thermopneumatic detector	when the radiation incident on a gas in a closed chamber increases the temperature and pressure of a gas, a mirror on the cell wall moves. This movement is measured optically, and can be used to determine the amount of radiation incident on the cell.
	thermovoltaic detector	an IR detector where temperature changes of a junction of dissimilar metals because of changes in the level of incident radiation causes a change in voltage.
उष्मागतिकी का तृतीय नियम	Third law of thermodynamics	The randomness of a system at 0 K is zero.
	time dilation	the idea that time travels slower for somebody in a moving reference frame; consequence of relativity.
	time-of-flight (TOF)	when you apply the same translational energy to all particles; the lighter particles will travel a shorter distance over a charged plate because there is less momentum to carry them forward.
	titration	When the concentration of an acid or base is determined by neutralizing it.
	total binding energy	energy required to break a nucleus into its component protons and neutrons
	total internal reflection second harmonic generation (TIR SHG)	This is what happens when you shine the exitation beam and probe beam on a liquid-liquid surface. What you are counting on happening is that the beams will reflect off of the bottom liquid and give the second harmonic signal you’re looking for.
	transducer	a device that turns one kind of energy to another (like a loudspeaker turns electrical energy to sound); a device that converts a light signal into an electrical signal
	transient grating techniques	what you do in one of these studies is to get several beams coming into a sample that have different circular polarity. Their interference sets up a diffraction grating which can be used to run experiments.
	transistor	a device used to give current and power amplification
	transition state	See "activated complex"
	transverse relaxation time (T2)	the time it takes after a pulse in NMR for the spins to get out of phase with one another. This is also called the spin-spin relaxation time.
	transverse wave	when a wave has the property that the particles of the wave move perpindicular to the motion of the wave itself, such as a water wave.
	TREPR	time-resolved electron paramagnetic resonance; a way of identifying transient radicals
	trichroism	exhibits different colors in 3 different directions when viewed by transmitted light
	triple point	The temperature and pressure at which all three states of a substance can exist in equilibrium.
	tungsten filament	an IR light source where the emitter is a tungsten filament; the IR output range is limited by the window material, although the window material may actually heat up enough to serve as a blackbody emitter.
	tunneling	the penetration of a particle into a classically-forbidden region.
	turbulent flow	when a moving liquid exhibits erratic, whirlpool-like currents.
	Turing pattern	patterns that arise from oscillatory coupled cells. AI.
	two-dimensional NMR	A method in which you can take NMR peaks that are stuck on top of each other and separate them. The plot has one axis as the normal NMR axis, and the other corresponds to the spectrum when you hit the sample with 90 degree radiation.
	Tyndall effect	the scattering of visible light by a colloidal dispersion.
	UHV	ultrahigh vacuum
	ultrasonic	sound waves that have frequency higher than we can hear (20,000 Hz)
	uniphase	a wavefront is uniphase if it has the same phase at all points
	unipotential lens	see einzel lens
	unit cell	The simplest part of a crystal that can be repeated over and over to make the whole thing.
असंतृप्त	unsaturated	When you haven't yet dissolved all of the solute that's possible to dissolve in a liquid.
	unshared electron pair	two electrons that aren't involved in chemical bonding. Also frequently referred to as a "lone pair".
	Vacuum ultraviolet (VUV)	UV radiation of high enough frequency that air will absorb it. UHV is ultrahigh vacuum-UV, which is of higher frequency still.
	valence electron	The outermost electrons in an atom.
	Van der Waals picture of condensed matter	molecular dynamics of dense fluids are determined primarily by the size and shape of molecules; that is, the short-range repulsive internuclear forces.
वाष्प दाब	vapor pressure	The pressure of a substance that's present above it's liquid. For example, you can tell that ammonia has a high vapor pressure because the smell of it is very strong above liquid ammonia.
वाष्पन	vaporization	When you boil a liquid.
	vector	a quantity that has both direction and magnitude, such as velocity.
	velocity selector	used with molecular beams; slotted disks that make sure only particles with the desired speed reach the target.
	Venturi tube	a pipe with a narrow constriction; if it has an opening at this constriction, it will tend to pull a vacuum through it equal to the vapor pressure of the liquid; a consequence of Bernoulli’s principle
	viscosity	the internal friction of a liquid
	visible spectrum	radiation of wavelength 400-750 nm.
	volatile	A substance with a high vapor pressure.
	voltage	equal to the potential difference between two things.
	VOM	volt-ohm-meter; a multimeter that measures voltage, current and resistance
	VSEPR	A theory for predicting molecular shapes that assumes that electrons like to be as far from each other as possible.
	Walden reductor	a metal reduction column filled with silver
	Walsh diagram	a diagram that shows the variation of orbital energy with molecular geometry
	Wedge prism	used for beam steering
	Welsbach mantle	a gauze mesh, similar to the one in gas lanterns, impregnated with ThO2 and a small amount of CeO2 which is heated by either a burning gas or electric charge. It gives off IR radiation between 10-100 microns.
	X-ray fluorescence spectroscopy (XRF)	measures the energies of the inner electrons of an atom by knocking them off with X-rays; good for about 35 elements. Handy because it is not a destructive method of analysis - the electrons are simply elevated to outer orbitals and the relaxation to the inner orbitals is measured.
	Young’s modulus (E)	the ratio of longitudinal stress to longitudinal strain.
	Zeeman effect	this is the effect of overcoming the normal degeneracy of electron spin states by applying a magnetic field which can interact with the magnetic moment of the electron. This is observed when atoms are subjected to a powerful magnetic field resulting in the spectral lines being split into a number of component lines.
	zeroth law of thermodyamics	If A is in thermal equilibrium with B and B is in thermal equilibrium with C, then A and C are in thermal equilibrium
	ZSM-5 zeolites	Commonly used zeolites which are extremely good at removing NOx. Used in auto emissions control and direct composition of NO to N2 and O2.